By Donald A. McQuarrie
Developed from McQuarrie and Simon's best-selling textbook, actual Chemistry: A Molecular process, this article follows an identical course by way of first masking the rules of quantum mechanics sooner than attractive these principles within the next improvement of thermodynamics. even if some of the chapters in Molecular Thermodynamics are just like chapters within the actual chemistry textual content, new fabric has been further all through besides 3 completely new chapters. The textual content comprises 5 brief "MathChapters," each one with a unique set of difficulties that may aid scholars assessment and summarize the mathematical instruments required to grasp the fabric. labored examples and chapter-ending issues of strategies also are incorporated through the publication.
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Sample text
1 1974 WJKW V, LAW. - bw units Ialr r,llnrrlllcllur. 'fhc ~tlcitlgas w l u t of V i c w b w R T / P 0,1211. , our inilia1 gutas. In {hi!. 043067 d n ~ ~ . m u lfor - ' melhanc. 5 by V - h and solve for P , we ohtain 1 IK r n ( r t t r h r r b t r I vrlw br 1) (11I 1. IIIUI~ I '1'11~C ; I ~ C U ~ ~ I ~ Oof I ~ prehburc preceding this rnilrnihr pawl ttw Imk t t l ~ 4 4~ ~~h c~vi1111r11r t ~ In th~xenumpk: show [hat the van der Wads rtlttunalrl, u IIIIF1 1 u ~111 r IUIMIC thi~ri ttlc ~tkal-gakequation, is nut panicul;uIy acctirnle.
1 pawal (Pa) = I N . 1 MPa , S-' Chapter 2 1 The Prupertirs [if (;ASH 2-1. 16 K. (We will learn about the pnlperties of a "triple point" in Chapter 9. c gas, l i c l ~ ~ i d and . 16 K. A kelvin is thcn defined aa 11273. l h of ttie temperature of the triple point of watcr These definitiuns of 0 K ;ind 271. Ih K generille a linear temperature sci~le. 1 plots cxlxrilnental -V versuh T for Ar(g) at dill~rrvrilI)rv**ktrcs. s 'V + U. The kelvin scalc i s related t o lhc corlirnorily uwd C'clhi~h~c:IIL.
R~t;~l \:lluc\ 111 H : , I 1 ' ) - divide them by 2rsu3~ , / 3 and , then pIot thc data vrrcllc I' X ,I I/ r , t l ~ r u s i ~lor l ~ nll gases will fall on one curve. 15 (or better yrl. c;~l 1:ihlcc) c:u~he used to evaluate B , , ( T ) for any gas. 2 6. London Oispers~onForr es Arc Otten the Largest Cuntributkin lo thcr y,cdl at pressures such that the contrihulion r,l and the ideal-gas value cwfticient i s ncgligihle. I k' ,,b -I I E X A M P L E 2-10 Estilnnte H,,{T)for N,(g]at 0 C'. 1 K and 2 r r t r ' ~ , / .