Download Encyclopedia of Electrochemistry, Thermodynamics and by Allen J. Bard, Martin Stratmann, Eliezer Gileadi, Michael PDF

By Allen J. Bard, Martin Stratmann, Eliezer Gileadi, Michael Urbakh

From basic learn to its program within the undefined, this encyclopedia covers all features of electrochemistry. It offers either a finished assessment for electrochemists and an obtainable examine electrochemical themes for clients from different medical disciplines. quantity 1 during this sequence deals an in depth exam of thermodynamics and electrified interfaces.

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Extra info for Encyclopedia of Electrochemistry, Thermodynamics and Electrified Interfaces

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01 M solutions, whose difference is inside the experimental error dispersion over the whole range of the electrode charges. This comparison enables one to conclude that the deviation of the data for the highest concentration at high positive charges is probably due to the violation of some assumption of the model, for example, dissolution of mercury or specific adsorption of cations. The concentration dependence of the diffuselayer capacitance is probably too weak to explain this divergence, see in following text, even if the GC theory may be inapplicable quantitatively.

21a) and (21b), is growing with the increase of the absolute value of the charge and with the concentration. c. 001 M aqueous solution of a 1,−1 electrolyte. c. As a result, for sufficiently concentrated solutions, about 1 M or higher, the diffuselayer contribution in Eq. (20) represents in most cases only a minor correction to the compact-layer term. Then, one can even use the simple Helmholtz model for qualitative interpretation of the data. , this approximation is acceptable for all concentrations.

2, and the definitions in Eqs. (23a) and (23b). Error bars for the experimental curves correspond to those in Fig. 2. immediately calculated from the theoretically derived ion concentration profiles. Although drastic deviations from the GC model have been predicted in these theories, no attempts have been made to subject them to the high precision experimental verification in accordance with Eq. (23b). 1 Electrochemical Interfaces: At the Border Line One should avoid, however, the mistake of interpreting the success of the GC passage through this test as its complete confirmation, in particular the proof of the validity of Eq.

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