By S. F. Sun(auth.)
Integrating assurance of polymers and organic macromolecules right into a unmarried textual content, Physical Chemistry of Macromolecules is thoroughly dependent to supply a transparent and constant source for rookies and execs alike. the elemental wisdom of either biophysical and actual polymer chemistry is roofed, in addition to vital phrases, simple structural homes and relationships.
This publication contains finish of bankruptcy difficulties and references, and likewise:
- Enables clients to enhance easy wisdom of biophysical chemistry and actual polymer chemistry.
- Explores absolutely the rules of macromolecular chemistry, equipment for choosing molecular weight and configuration of molecules, the constitution of macromolecules, and their separations.Content:
Chapter 1 advent (pages 1–18):
Chapter 2 Syntheses of Macromolecular Compounds (pages 19–51):
Chapter three Distribution of Molecular Weight (pages 52–66):
Chapter four Macromolecular Thermodynamics (pages 67–95):
Chapter five Chain Configurations (pages 96–126):
Chapter 6 Liquid Crystals (pages 127–149):
Chapter 7 Rubber Elasticity (pages 150–164):
Chapter eight Viscosity and Viscoelasticity (pages 165–197):
Chapter nine Osmotic strain (pages 198–222):
Chapter 10 Diffusion (pages 223–242):
Chapter eleven Sedimentation (pages 243–266):
Chapter 12 Optical Rotatory Dispersion and round Dichroism (pages 267–283):
Chapter thirteen High?Performance Liquid Chromatography and Electrophoresis (pages 284–319):
Chapter 14 mild Scattering (pages 320–347):
Chapter 15 Fourier sequence (pages 348–370):
Chapter sixteen Small?Angle X?Ray Scattering, Neutron Scattering, and Laser mild Scattering (pages 371–398):
Chapter 17 digital and Infrared Spectroscopy (pages 399–435):
Chapter 18 Protein Molecules (pages 436–454):
Chapter 19 Nuclear Magnetic Resonance (pages 455–496):
Chapter 20 X?Ray Crystallography (pages 497–534):
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Additional info for Physical Chemistry of Macromolecules: Basic Principles and Issues, Second Edition
Sample text
Physical Chemistry of Surfaces, 2nd ed. New York: Wiley-Interscience, 1967. 18 INTRODUCTION Billmeyer, F. , Textbook of Polymer Chemistry, 2nd ed. New York: Wiley, 1985. Carothers, W. , J. Am. Chem. Soc. 51, 2548 (1929). , and K. Simons, Biochim. Biophys. Acta 415, 29 (1975). Shaw, D. , Introduction to Colloids and Surface Chemistry, 2nd ed. Stoneham, MA: Butterworth, 1978. , The Hydrophobic Effect. New York: Wiley, 1981. 2 SYNTHESES OF MACROMOLECULAR COMPOUNDS The first three sections of this chapter deal with addition polymerization, the fourth with condensation polymerization, the fifth with kinetics of the syntheses of polymers, the sixth with polypeptide synthesis, and the seventh with nucleic acid synthesis.
If an alkene, such as ethylene, is introduced, the alkene attaches itself to titanium by a p bond. With the alkene and ethyl both held by the metal, the alkene unit inserts itself between the metal and the ethyl group. There is now an n-butyl group (in the case of ethylene) attached to the titanium. The bonding site where ethylene was held is vacant. The catalyst is ready to work again and the process continues until the insertion of hydrogen. The long chain then separates from the metal and a molecule of polyethylene has been formed.
New York: Wiley-Interscience, 1967. 18 INTRODUCTION Billmeyer, F. , Textbook of Polymer Chemistry, 2nd ed. New York: Wiley, 1985. Carothers, W. , J. Am. Chem. Soc. 51, 2548 (1929). , and K. Simons, Biochim. Biophys. Acta 415, 29 (1975). Shaw, D. , Introduction to Colloids and Surface Chemistry, 2nd ed. Stoneham, MA: Butterworth, 1978. , The Hydrophobic Effect. New York: Wiley, 1981. 2 SYNTHESES OF MACROMOLECULAR COMPOUNDS The first three sections of this chapter deal with addition polymerization, the fourth with condensation polymerization, the fifth with kinetics of the syntheses of polymers, the sixth with polypeptide synthesis, and the seventh with nucleic acid synthesis.